Mechanical damage to bone generates organic free radicals at the fracture surfaces which are readily converted into peroxy radicals. These radicals, characterised by EPR spectroscopy, are formed by homolytic breakage of collagen strands.
R. Partridge, M. C. R. Symons and J. L. Wyatt, J. Chem. Soc., Faraday Trans., 1993, 89, 1285 DOI: 10.1039/FT9938901285
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