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Issue 19, 1993
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Excited-state properties and reactivity of [ReCL(CO)3(2,2′-bipy)](2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy

Abstract

Fast time-resolved infrared spectroscopy shows that the v(CO) bands of the important CO2-reducing complex, [ReCl(CO)3(2,2′-bipy)]1(2,2′-bipyridyl), shift up in frequency in the metal to ligand charge-transfer excited state and that the anion 1, generated by reaction of the excited state with triethylamine, shows a lowering in frequency of the v(CO) bands significantly different from those of related but non-reducing complexes.

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Article type: Paper
DOI: 10.1039/DT9930002977
Citation: J. Chem. Soc., Dalton Trans., 1993,0, 2977-2979

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    Excited-state properties and reactivity of [ReCL(CO)3(2,2′-bipy)](2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy

    M. W. George, F. P. A. Johnson, J. R. Westwell, P. M. Hodges and J. J. Turner, J. Chem. Soc., Dalton Trans., 1993, 0, 2977
    DOI: 10.1039/DT9930002977

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