Studies using the Cambridge Structural Database have shown that hydrogen-bond linearity is a major factor determining the structure of halide ion pairs bridged by water and NH2-containing molecules and that the halide–halide distances in these ion pairs are geometrical consequences of this fact.
S. S. Pathaneni and G. R. Desiraju, J. Chem. Soc., Dalton Trans., 1993, 2505 DOI: 10.1039/DT9930002505
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