Issue 14, 1993
From the journal:

Journal of the Chemical Society, Dalton Transactions

Silver(I) oxide-mediated syntheses of four-membered ring platinalactones

William Henderson,   Raymond D. W. Kemmitt  and  Adrienne L. Davis  

Abstract

Reaction of cis-[PtCl2(PPh3)2] with an excess of dialkyl malonate in the presence of silver(I) oxide afforded the platinalactone complexes [[graphic omitted]H(CO2R)}(PPh3)2](R = Me or Et), via a novel cyclisation reaction. The platinalactone complexes have been fully characterised by NMR spectroscopy. Functionalised acetic acids containing activated hydrogens may also be used to synthesise four-membered ring platinalactones.

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Article information

DOI
https://doi.org/10.1039/DT9930002247
Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 2247-2250

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Silver(I) oxide-mediated syntheses of four-membered ring platinalactones

W. Henderson, R. D. W. Kemmitt and A. L. Davis, J. Chem. Soc., Dalton Trans., 1993, 2247 DOI: 10.1039/DT9930002247

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