Spectroscopic data, particularly 57Fe Mössbauer, and X-ray powder diffraction data are presented for a series of salts [NR4]2[FeCl4] and for doped materials of [NMe4]2[FeCl4] and [NMe4]2[CoCl4] in different ratios. The effect of the cation on the electronic environment of the iron is discussed in terms of direct charge effects and lattice dynamics.
E. Slade, A. Houlton, J. Silver, D. J. Evans and G. J. Leigh, J. Chem. Soc., Dalton Trans., 1993, 1217 DOI: 10.1039/DT9930001217
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