Issue 6, 1993

Dalton communications. Structure of the [SbI4{Me2P(CH2)2PMe2}] anion: structural evidence for an arrested double SN2 substitution

Abstract

The antimony centre in the structurally characterised complex [H(py)2][SbI4(dmpe)][py = pyridine, dmpe = 1,2-bis(dimethylphosphino)ethane] shows significant distortions from octahedral geometry which are discussed in terms of an arrested double SN2 transition state for the nucleophilic substitution of two iodide anions by dmpe.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 997-998

Dalton communications. Structure of the [SbI4{Me2P(CH2)2PMe2}] anion: structural evidence for an arrested double SN2 substitution

W. Clegg, M. R. J. Elsegood, V. Graham, N. C. Norman and N. L. Pickett, J. Chem. Soc., Dalton Trans., 1993, 997 DOI: 10.1039/DT9930000997

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