Issue 4, 1993

Syntheses, spectroscopy and electrochemistry of nitridorhenium(V) organometallics. X-Ray crystal structure of [ReVNMe2(PPh3)2]

Abstract

Treatment of [ReVNCl2(PPh3)2] with LiR gives the complexes [ReVNR2(PPh3)2](R = Me, C[triple bond, length as m-dash]CBut, Ph or C6H4Me-p) which show rich photophysical behaviour; the crystal structure of [ReVNMe2(PPh3)2] exhibits a Re[triple bond, length as m-dash]N distance of 1.641 (4)Å.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 651-652

Syntheses, spectroscopy and electrochemistry of nitridorhenium(V) organometallics. X-Ray crystal structure of [ReVNMe2(PPh3)2]

V. W. Yam, K. Tam and T. Lai, J. Chem. Soc., Dalton Trans., 1993, 651 DOI: 10.1039/DT9930000651

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