Reaction of an ethanolic solution of p-anisaldehyde thiosemicarbazone (HL) with an aqueous [TlMe2(OH)] solution afforded the compound [TIMe2L] in which the deprotonated thiosemicarbazone retains the typical structure of free thiosemicarbazones, an unusual arrangement of this type of ligand in a metallic complex.
J. S. Casas, E. E. Castellano, A. Macías, M. C. Rodríguez-Argüelles, A. Sánchez and J. Sordo, J. Chem. Soc., Dalton Trans., 1993, 353 DOI: 10.1039/DT9930000353
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