Issue 24, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Redox-active organometallic Ir complexes containing biphenyl-2,2′-diyl

Zheng Lu,   Chul-Ho Jun,   Susan R. de Gala,   Michel Sigalas,   Odile Eisenstein  and  Robert H. Crabtree  

Abstract

The redox-active complexes [Ir(PPh3)2(biph)Cl]3 and [Ir(PMe3)3(biph)Cl]6 contain biphenyl-2,2-diyl (biph), the organometallic analogue of bipy; 3 shows an unexpected five-coordinate structure lying between T and Y geometry and oxidation of 6 by NOBF4 gives [Ir(PMe3)3(biphBF)Cl]+(8)+, an unprecedented IrIV boryl complex.

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Article information

DOI
https://doi.org/10.1039/C39930001877
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1877-1880

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Redox-active organometallic Ir complexes containing biphenyl-2,2′-diyl

Z. Lu, C. Jun, S. R. de Gala, M. Sigalas, O. Eisenstein and R. H. Crabtree, J. Chem. Soc., Chem. Commun., 1993, 1877 DOI: 10.1039/C39930001877

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