Issue 24, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analogue of the Creutz–Taube ion

Wolfgang Bruns,   Wolfgang Kaim,   Eberhard Waldhör  and  Michael Krejčik  

Abstract

The dinuclear complex ion trans,mer-[(PPri3)2(CO)3Mo(µ-pz)Mo(CO)3(PPri3)2]+(pz = pyrazine), the closest yet reported organometallic analogue of the Creutz–Taube ion [(NH3)5Ru(µ-pz)Ru(NH3)5]5+, has been characterized as a fully delocalized Mo0.5/Mo0.5 system by electrochemistry, EPR, electronic and vibrational absorption spectroscopy.

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Article information

DOI
https://doi.org/10.1039/C39930001868
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1868-1869

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Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analogue of the Creutz–Taube ion

W. Bruns, W. Kaim, E. Waldhör and M. Krejčik, J. Chem. Soc., Chem. Commun., 1993, 1868 DOI: 10.1039/C39930001868

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