Issue 24, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Crystal structure of [Rh2(µ2-O2CMe)2{µ2-(CH2)PPh2}{µ2-(C6H4)PPh2}·PPh3]·2CH2Cl2, a compound with a diphenylphosphinomethanide group in a bridging (P,C) coordination

M. Victoria Borrachero,   Francisco Estevan,   Santiago García-Granda,   Pascual Lahuerta,   Julio Latorre,   Eduardo Peris  and  Mercedes Sanaú  

Abstract

The reaction of the monometallated compound [Rh2(µ2-O2CMe)3{µ2-(C6H4)PMePh}·(HO2CMe)2] and two moles of PPh3 yields [Rh2(µ2-O2CMe)2{µ2-CH2PPh2}{µ2-(C6H4)PPh2}PPh3]·2CH2Cl2 which according to the crystal structure contains an orthometallated triphenylphosphine and a diphenylphosphinomethanide group bridging the two rhodium atoms.

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Article information

DOI
https://doi.org/10.1039/C39930001864
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1864-1865

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Crystal structure of [Rh2(µ2-O2CMe)2{µ2-(CH2)PPh2}{µ2-(C6H4)PPh2}·PPh3]·2CH2Cl2, a compound with a diphenylphosphinomethanide group in a bridging (P,C) coordination

M. V. Borrachero, F. Estevan, S. García-Granda, P. Lahuerta, J. Latorre, E. Peris and M. Sanaú, J. Chem. Soc., Chem. Commun., 1993, 1864 DOI: 10.1039/C39930001864

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