seco-Taxane 8, a potential starting material for further development into highly substituted taxanes, is synthesized by BF3·OEt2 treatment of epoxy-allylsilane 7, in its turn synthesized by joining an A-ring derivative 2 with a C-ring precursor chain 3.
L. Pettersson and T. Frejd, J. Chem. Soc., Chem. Commun., 1993, 1823 DOI: 10.1039/C39930001823
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