A miniature flow reactor has been developed for photochemical reactions in supercritical fluids; [Cr(CO)5(C2H4)] is isolated, for the first time, by the UV photolysis of [Cr(CO)6] in supercritical C2H4 at room temp, with a yield of ca. 40 mg per hour at ca. 80% purity as estimated by IR spectroscopy.
J. A. Banister, S. M. Howdle and M. Poliakoff, J. Chem. Soc., Chem. Commun., 1993, 1814 DOI: 10.1039/C39930001814
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