Neutral, bis-complexes of oxovanadium(IV) with salicylaldoximes and salicylketoximes react with a range of nitriles to afford a novel organic ligand type; the prototypical reaction product [VVO2{C6H4(O)CH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N–OC(Me)NH}] is characterised by single crystal X-ray diffraction and spectroscopic studies.
J. Grigg, D. Collison, C. D. Garner, M. Helliwell, P. A. Tasker and J. M. Thorpe, J. Chem. Soc., Chem. Commun., 1993, 1807 DOI: 10.1039/C39930001807
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