The acidolysis of trialkyltin allylic sulfinates yields the corresponding sulfinic acids which undergo a first-order thermal decomposition with γ-syn substitution as predicted for a retro-ene mechanism.
M. D. King, R. E. Sue, R. H. White and D. J. Young, J. Chem. Soc., Chem. Commun., 1993, 1797 DOI: 10.1039/C39930001797
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