Issue 24, 1993

A new mode of reactivity for nitrile ylides?

Abstract

Treatment of the imidoyl chlorides 4 with base afforded the imidazoles 6; these formal dimerisation products are the opposite regioisomers to those predicted by an analysis of the frontier molecular orbitals for the cycloaddition of the nitrile ylides 5 to their imidoyl chloride 4 precursors.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1789-1790

A new mode of reactivity for nitrile ylides?

P. W. Groundwater, A. J. Morton and R. Salter, J. Chem. Soc., Chem. Commun., 1993, 1789 DOI: 10.1039/C39930001789

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