Issue 22, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Reaction of CO and tert-butyl isocyanide with the cluster [(C5Me5)3Co3(µ2-H)3(µ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3(µ-H)(µ3-η2-HC[double bond, length half m-dash]NCMe3)]

Charles P. Casey,   Ross A. Widenhoefer,   Susan L. Hallenbeck  and  James A. Gavney, Jr.  

Abstract

The reaction of [(C5Me5)3Co3(µ-2-H)3(µ3-H)]1 with 2 equiv. of CO forms the biscarbonyl dihydride cluster [(C5Me5)3Co3(µ3-CO)(µ2-CO)(µ-H)2]2; tert-butyl isocyanide inserts into a Co–H bond of 1 to form the formimidoyl monohydride cluster [(C5Me5)3Co3(µ-H)(µ3-η2-HC[double bond, length half m-dash]NCMe3)]5, via the intermediate [(C5Me5)3Co3(µ3-CNCMe3)(µ2-CNCMe3)(µ-H)2]6.

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Article information

DOI
https://doi.org/10.1039/C39930001692
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1692-1694

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Reaction of CO and tert-butyl isocyanide with the cluster [(C5Me5)3Co3(µ2-H)3(µ3-H)] facile hydrogen transfer to isocyanide forms [(C5Me5)3Co3(µ-H)(µ3-η2-HC[double bond, length half m-dash]NCMe3)]

C. P. Casey, R. A. Widenhoefer, S. L. Hallenbeck and J. A. Gavney, J. Chem. Soc., Chem. Commun., 1993, 1692 DOI: 10.1039/C39930001692

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