Highly Stereoselective C–C bond formation occurred in the reaction of 2,3-isopropylidenedioxycycfohexanone oxime esters with organoaluminium reagents and the reaction was applied to the syntheses of (±)-endo-brevicomin and the synthetic intermediate of (±)-juvenile hormone.
H. Fujioka, M. Miyazaki, H. Kitagawa, T. Yamanaka, H. Yamamoto, K. Takuma and Y. Kita, J. Chem. Soc., Chem. Commun., 1993, 1634 DOI: 10.1039/C39930001634
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