Issue 21, 1993

The first example of the generation of acylselenenyl halides from Se-arsanyl selenoesters: application to the synthesis of Se-β-oxoalkyl selenoesters

Abstract

Acylselenenyl halides 2(X = Cl, Br) have been generated from RC(O)SeAsPh21 and N-halogenosuccinimide, and the chlorides 2(X = Cl) have been treated with enol silyl ethers to give Se-β-oxoalkyl Selenoesters 5 in good yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1631-1632

The first example of the generation of acylselenenyl halides from Se-arsanyl selenoesters: application to the synthesis of Se-β-oxoalkyl selenoesters

T. Kanda, K. Mizoguchi, T. Koike, T. Murai and S. Kato, J. Chem. Soc., Chem. Commun., 1993, 1631 DOI: 10.1039/C39930001631

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