Palladium-catalysed methylation of diethyl phosphates derived from optically active γ-trimethylsilylallyl alcohols proceeds in a highly regio- and stereo-selective manner to give optically active vinylsilanes having an allylic methyl group.
H. Urabe, H. Inami and F. Sato, J. Chem. Soc., Chem. Commun., 1993, 1595 DOI: 10.1039/C39930001595
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