The synthesis and characterization of two novel octanuclear mixed-metal clusters: [CrM3O4(O2CEt)8]2Na2(M
Mo,W)
Abstract
Two novel insoluble octanuclear mixed-metal clusters with a centrosymmetric [M3O4CrCrO4M3]14+(M
Mo,W) core have been synthesized and characterized; a strong absorption near zero magnetic field in the EPR spectrum of the CrW3 cluster is unexpectedly observed.
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Mo,W)