Issue 19, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

Isolation and characterization of a vanadium ethylidyne complex. The crystal structure of [(Cy2N)2Li(µ3-O)(µ2,η1:η1CMe) an unusual V2LiO cluster

Sandro Gambarotta,   Jilles J. H. Edema  and  Ravinder K. Minhas  

Abstract

Reaction of VCI2(TMEDA)2[TMEDA =N,N,N′,N′-tetramethylenediannine] with Cy2NH [Cy = cyclohexyl] and BunLi in tetrahydrofuran led to the formation of a complicated mixture of products from which a dinuclear ethylidyne complex [(Cy2N)2V]2(µ3η1-O)(µ2,η1:η1-CMe)1was isolated

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Article information

DOI
https://doi.org/10.1039/C39930001503
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 1503-1504

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Isolation and characterization of a vanadium ethylidyne complex. The crystal structure of [(Cy2N)2Li(µ3-O)(µ2,η1:η1CMe) an unusual V2LiO cluster

S. Gambarotta, J. J. H. Edema and R. K. Minhas, J. Chem. Soc., Chem. Commun., 1993, 1503 DOI: 10.1039/C39930001503

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