Versatile behaviour of the phosphanyl salt (Pri2N)2 P+CF3SO3– towards zirconocene derivatives
Abstract
Transfer reactions of various groups (Ph2P[CH2]3–, Ph2CCPh–CHN–, N3, CN, Me, Cl, H) occurred from zirconium to phosphorus in reactions of the phosphanylium salt (Pri2N)2 P+CF3SO3– with zirconocene derivatives; the crystal structure of (Pri2N)2P–CHN–P(NPri2)28 has been determined.