Semiempirical geometry optimization of triindenotriphenylene predicts a rigid cup-shaped structure with strain-induced bond alternation in the central benzenoid ring; model studies of the corresponding Li complex suggest that metal coordination occurs preferentially from the convex side of the bowl.
R. Faust and K. P. C. Vollhardt, J. Chem. Soc., Chem. Commun., 1993, 1471 DOI: 10.1039/C39930001471
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