Water-soluble rhodium-phosphane complexes are very efficient catalysts for the hydrogenation of carbon dioxide to formic acid in water–amine mixtures similar to those used for separation of CO2 from flue gases.
F. Gassner and W. Leitner, J. Chem. Soc., Chem. Commun., 1993, 1465 DOI: 10.1039/C39930001465
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