SCHEDULED MAINTENANCE
The species [Pt(dien)(sgh-S)]2+1 formed upon reaction of sgh with one equivalent of (PtCl(dien)Cl at 2 < pH < 6.5 is found to isomerize intramolecularly into [Pt(dien)(sgh-N7)]2+2 with Pt coordination at N7 of guanosine; upon addition of a second equivalent of [PtCL(dien)]Cl dinuclear [{Pt(dien)}2(sgh-N7,S)]4+3 is formed.
S. S. G. E. van Boom and J. Reedijk, J. Chem. Soc., Chem. Commun., 1993, 1397 DOI: 10.1039/C39930001397
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