(+)-(1R)-Nopinone 1, in conjunction with a Lewis acid and an electron donor (N,N-dimethylacetamide or triethylamine) in CH2Cl2, initiates the polymerisation of isobutylene at –40 °C resulting in the formation of a new α,ω-asymmetric telechelic poly(isobutylene) of low polydispersity.
P. Gullapalli and J. P. Heller, J. Chem. Soc., Chem. Commun., 1993, 1384 DOI: 10.1039/C39930001384
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