The course of the dehydration of α-hydroxy-γ-oxotrimethylsilanes is highly dependent on the conditions to produce stereoselectively (Z)- and (E)-γ-oxovinyltrirnethylsilanes, which are potential precursors for preparation of stereodefined exocyclic tetrasubstituted alkenes.
K. Nakatani, T. Izawa, Y. Odagaki and S. Isoe, J. Chem. Soc., Chem. Commun., 1993, 1365 DOI: 10.1039/C39930001365
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