The reaction of anti-alkyl thiirane S-oxides 1 with hindered amide bases affords trans-substituted ethenesulfenate anions viaa deprotonation–ring-opening sequence.
A. L. Schwan, M. F. Pippert, H. H. Pham and M. R. Roche, J. Chem. Soc., Chem. Commun., 1993, 1312 DOI: 10.1039/C39930001312
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