On treatment with tributyltin hydride and azoisobutyronitrile in benzene at reflux α-aryl-β-bromoalkyl vinyl ethers rearrange in moderate yield to δ-aryl ketones: possible mechanistic rationales are discussed for this novel C–C bond-forming process.
D. Crich and Q. Yao, J. Chem. Soc., Chem. Commun., 1993, 1265 DOI: 10.1039/C39930001265
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