The tantalum monohydride compound [Ta(OAr)2Cl2(H)(PMe2Ph)2](OAr = 2,6-diisopropylphenoxide) will react with one, two or three equivalents or organic isocyanides to produce a sequence of organometallic products resulting from initial insertion into the Ta–H bond and subsequent coupling reactions.
J. R. Clark, P. E. Fanwick and I. P. Rothwell, J. Chem. Soc., Chem. Commun., 1993, 1233 DOI: 10.1039/C39930001233
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