Generation of a novel type of organotin enolate has been accomplished by the regioselective ring cleavage of diketene with bis(tributyltin) oxide; the enolate afforded the first example of Michael addition in reactions using organotin(IV) enolates.
I. Shibata, M. Nishio, A. Baba and H. Matsuda, J. Chem. Soc., Chem. Commun., 1993, 1067 DOI: 10.1039/C39930001067
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