Treatment of π-allyl-palladium and -platinum complexes bearing a methoxymethoxy group at the 2-position with base give the corresponding oxodimethylenemethane complexes, in contrast to the formation of 2-hydroxy-substituted π-allyl complexes via acidic hydrolysis.
A. Ohsuka, T. Fujimori, T. Hirao, H. Kurosawa and I. Ikeda, J. Chem. Soc., Chem. Commun., 1993, 1039 DOI: 10.1039/C39930001039
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