Cyclophellitol and its (1R,6S)-, (1R,2S,6S)-, (2S)-diastereoisomers are constructed from quinic acid involving a regioselective cyclic sulfate ring opening reaction, a regiospecific oxidative elimination, and an epoxidation reaction.
T. K. M. Shing and V. W.-F. Tai, J. Chem. Soc., Chem. Commun., 1993, 995 DOI: 10.1039/C39930000995
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