Issue 11, 1993

Stereoselective template-directed C-glycosidation. Synthesis of bicyclic ketooxetanes via intramolecular cyclization reactions of (2-pyridylthio)glycosidic silyl enol ethers

Abstract

Bicyclic ketooxetanes 5a, 5b and 8 are formed with excellent stereoselectivity on treatment of (2-pyridylthio)glycosidic silyl enol ethers 1a, 1b and 2 with silver(I) trifluoromethanesulfonate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 901-903

Stereoselective template-directed C-glycosidation. Synthesis of bicyclic ketooxetanes via intramolecular cyclization reactions of (2-pyridylthio)glycosidic silyl enol ethers

D. Craig and V. R. N. Munasinghe, J. Chem. Soc., Chem. Commun., 1993, 901 DOI: 10.1039/C39930000901

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