Issue 10, 1993

Reactivity studies on tantalocene(sulfido)hydride Cp′2Ta([double bond, length half m-dash]S)H (Cp′= ButC5H4): cycloaddition on and protonation of the Ta[double bond, length half m-dash]S ligand

Abstract

Reactions of the tantalocene(sulfido)hydride Cp′2Ta([double bond, length half m-dash]S)H with PhNCS and HCl exhibit a surprisingly low metal-hydride reactivity; the Ta[double bond, length half m-dash]S bond being involved either in a [2 + 2] cycloaddition or a protonation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 851-852

Reactivity studies on tantalocene(sulfido)hydride Cp′2Ta([double bond, length half m-dash]S)H (Cp′= ButC5H4): cycloaddition on and protonation of the Ta[double bond, length half m-dash]S ligand

H. Brunner, M. M. Kubicki, J. Leblanc, C. Moise, F. Volpato and J. Wachter, J. Chem. Soc., Chem. Commun., 1993, 851 DOI: 10.1039/C39930000851

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