The cluster [Os3(CO)10(µ-L)](L = Ph2PC5H4N)(X-ray structure reported), containing the diaxially coordinated 2-pyridyldiphenylphosphine bridge, undergoes rapid transfer of the pyridine between two metal atoms while the phosphorus atom remains firmly coordinated to the third.
A. J. Deeming and M. B. Smith, J. Chem. Soc., Chem. Commun., 1993, 844 DOI: 10.1039/C39930000844
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