Issue 9, 1993

Highly regioselective 7-endo-aryl radical cyclisation: synthesis of octahydro-2H-dibenzo[a,d]cycloheptenes

Abstract

A highly efficient 7-endo-trig-aryl radical cyclisation of the alkene 6 and the vinylcyclohexanols 11ad with tri-n-butyltin hydride leading to the respective octahydro-2H-dibenzo[a,d]cycloheptene derivatives 7 and 8 and 12ad is reported.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 809-811

Highly regioselective 7-endo-aryl radical cyclisation: synthesis of octahydro-2H-dibenzo[a,d]cycloheptenes

A. K. Ghosh, K. Ghosh, S. Pal and U. R. Chatak, J. Chem. Soc., Chem. Commun., 1993, 809 DOI: 10.1039/C39930000809

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