The metal–η3-2-methoxycarbonylpentadienyl complexes (C5R5)M(CO)2(syn-Ti3-2-COOMe-C6H5)(R![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
H, MW; RH, Me, M Mo) undergo a novel acid-catalysed cotrimerization with a- and (3-unsaturated ketones to afford two products with diastereoisomeric six-membered rings which have been structurally characterized by X-ray diffraction.
M. Cheng, S. Lin, J. Chow, G. Lee, S. Pengb and R. Liu, J. Chem. Soc., Chem. Commun., 1993, 757 DOI: 10.1039/C39930000757
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