Reaction of [(η5-RC5H4)2Fe2(CO)4] with isocyanides in the presence of a catalytic amount of triethylborane results in the selective monosubstitution of the CO ligand with the isocyanide; a radical chain process is proposed for the reaction.
S. Nakanishi, Y. Taniki and Y. Otsuji, J. Chem. Soc., Chem. Commun., 1993, 709 DOI: 10.1039/C39930000709
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