An EXAFS multishell analysis of a titanium silicalite with an MFI structure reveals that the double Si–O–Ti bridges formed between [TiOx] species and the [SiO4] framework tetrahedra are partially hydrolysed in the presence of water which results in the conversion from an edge- to a corner-sharing type of bonding between the two structural units.
L. Bonneviot, D. T. On and A. Lopez, J. Chem. Soc., Chem. Commun., 1993, 685 DOI: 10.1039/C39930000685
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