Octakis(3,6-anhydro)-γ-cyclodextrin 3 has been prepared by the reaction of octakis (6-O-tosyl)-γ- Cyclodextrin with KOH; 3 shows a specific binding ability to alkali metal ions with larger ionic diameters, owing to its hydrophilic cavity which is similar to the layered crown ethers.
H. Yamamura, T. Ezuka, Y. Kawase, M. Kawai, Y. Butsugan and K. Fujita, J. Chem. Soc., Chem. Commun., 1993, 636 DOI: 10.1039/C39930000636
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