Issue 6, 1993

Formation of a 4H-cyclopenta-1,2,3-thiadiazole by rearrangement of a transient N-(thionitroso)cyclopenta-2,4-diene-1-imine

Abstract

1-Diazo-2,3,4,5-tetrachlorocyclopenta-2,4-diene, 2, reacts with sulfur dichloride or with disulfur dichloride to form 4,4,5,6-tetrachloro-4H-cyclopenta-1,2,3-thiadiazole, 6, most likely via a transient N-(thionitroso)cyclopenta-2,4-diene-1-imine, 4.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 489-491

Formation of a 4H-cyclopenta-1,2,3-thiadiazole by rearrangement of a transient N-(thionitroso)cyclopenta-2,4-diene-1-imine

T. B. Christensen, K. A. Jørgensen, F. K. Larsen, L. Martiny, J. Møller, A. Senning and L. Vichi, J. Chem. Soc., Chem. Commun., 1993, 489 DOI: 10.1039/C39930000489

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