The reaction between H4Re4(CO)2 and methanol in chloroform, yielding H4Re4(CO)2(MeOH)4 at room temperature, is first order in H4Re4(CO)12 and fourth order in methanol; no intermediate was detected by UV–VIS and 1H NMR spectra.
S. R. Wang and C. P. Cheng, J. Chem. Soc., Chem. Commun., 1993, 470 DOI: 10.1039/C39930000470
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