Issue 4, 1993
From the journal:

Journal of the Chemical Society, Chemical Communications

A dibasic carbon centre: kinetic and thermodynamic studies on the deprotonation of trans-[MoCl(NCH2CO2Me)(Ph2PCH2CH2PPh2)2]+

Richard A. Henderson,   Saad K. Ibrahim  and  Christopher J. Pickett  

Abstract

A kinetic and thermodynamic analysis of the reaction between trans-[MoCl(NCHRCO2Me)(dppe)2]+(R = H or Me, dppe = Ph2PCH2CH2PPh2) and MeO– shows that when R = H both NCH2 protons are ionisable, with the pKas of trans-[MoCl(NCH2CO2Me)(ppe)2]+(pKa= 11.2) and trans-[MoCl(NCHCO)2Me(dppe)2](pKa= 11.5) being remarkably similar.

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Article information

DOI
https://doi.org/10.1039/C39930000392
Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 392-394

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A dibasic carbon centre: kinetic and thermodynamic studies on the deprotonation of trans-[MoCl(NCH2CO2Me)(Ph2PCH2CH2PPh2)2]+

R. A. Henderson, S. K. Ibrahim and C. J. Pickett, J. Chem. Soc., Chem. Commun., 1993, 392 DOI: 10.1039/C39930000392

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