Issue 4, 1993

Control of chelation/nonchelation stereoselections in lanthanide-catalysed aldol reactions

Abstract

A europium complex, [Eu(dppm)3], can ‘recognize’ the difference in not only the protecting groups of α- or β-alkoxy aldehydes but also the size of ketene silyl acetals and catalyse either the chelation or nonchelation controlled-aldol reaction; {[Eu(dppm)3]= tris[di(perfluoro-2-propoxypropionyl)methanato]europium(III)}.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 343-345

Control of chelation/nonchelation stereoselections in lanthanide-catalysed aldol reactions

K. Mikami, M. Terada and T. Nakai, J. Chem. Soc., Chem. Commun., 1993, 343 DOI: 10.1039/C39930000343

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