Asymmetric catalysis of the glyoxylate–ene reaction with vinylic sulfides and selenides by a binaphthol-derived titanium complex provides enantiomerically pure (e.p.) diastereoisomers (anti and Z) of β-alkyl-α-hydroxy esters.
M. Terada, S. Matsukawa and K. Mikami, J. Chem. Soc., Chem. Commun., 1993, 327 DOI: 10.1039/C39930000327
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