The phosphido-phosphinidene coordination mode Cof a P2 ligand has been realized in the trinuclear complex [(TaL)3(P4)(P2)]2(L = 1,3-But2C5H3); structural proof was obtained by X-ray structure determination of the [(TaL)3(P4{Fe(CO)4}MP2)] derivative 3.
O. J. Scherer, R. Winter and G. Wolmershäuser, J. Chem. Soc., Chem. Commun., 1993, 313 DOI: 10.1039/C39930000313
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