Agostic Pd ⋯ H+⋯ NHR2 and apical Pd ⋯ NHR2 interactions: the synthesis and structures of [PdIICl2(H[9]aneN3)]+, the PdII–PdII dimer [(H[9]aneN3)Cl2Pd–PdCl2(H[9]aneN3)]2+, and [Pd(Me3[9]aneN3)(NCMe)2]2+

Alexander J. Blake; Alan J. Holder; Yvonne V. Roberts; Martin Schröder

doi:10.1039/C39930000260

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Agostic Pd ⋯ H⁺⋯ NHR₂ and apical Pd ⋯ NHR₂ interactions: the synthesis and structures of [Pd^IICl₂(H[9]aneN₃)]⁺, the Pd^II–Pd^II dimer [(H[9]aneN₃)Cl₂Pd–PdCl₂(H[9]aneN₃)]²⁺, and [Pd(Me₃[9]aneN₃)(NCMe)₂]²⁺

Alexander J. Blake, Alan J. Holder, Yvonne V. Roberts and Martin Schröder

Abstract

Long-range agostic Pd ⋯ H⁺⋯ NHR₂ interactions are observed in the crystal structure of the protonated form of cis-[Pd^IICl₂([9]aneN₃)], while a direct apical Pd ⋯ NHR₂ interaction is observed in the purple complex [Pd(Me₃[9]aneN₃)(NCMe)₂](PF₆)₂.

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DOI: https://doi.org/10.1039/C39930000260
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1993, 260-262

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Agostic Pd ⋯ H⁺⋯ NHR₂ and apical Pd ⋯ NHR₂ interactions: the synthesis and structures of [Pd^IICl₂(H[9]aneN₃)]⁺, the Pd^II–Pd^II dimer [(H[9]aneN₃)Cl₂Pd–PdCl₂(H[9]aneN₃)]²⁺, and [Pd(Me₃[9]aneN₃)(NCMe)₂]²⁺

A. J. Blake, A. J. Holder, Y. V. Roberts and M. Schröder, J. Chem. Soc., Chem. Commun., 1993, 260 DOI: 10.1039/C39930000260

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Journal of the Chemical Society, Chemical Communications

Agostic Pd ⋯ H⁺⋯ NHR₂ and apical Pd ⋯ NHR₂ interactions: the synthesis and structures of [Pd^IICl₂(H[9]aneN₃)]⁺, the Pd^II–Pd^II dimer [(H[9]aneN₃)Cl₂Pd–PdCl₂(H[9]aneN₃)]²⁺, and [Pd(Me₃[9]aneN₃)(NCMe)₂]²⁺

Abstract

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Download Citation

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Agostic Pd ⋯ H⁺⋯ NHR₂ and apical Pd ⋯ NHR₂ interactions: the synthesis and structures of [Pd^IICl₂(H[9]aneN₃)]⁺, the Pd^II–Pd^II dimer [(H[9]aneN₃)Cl₂Pd–PdCl₂(H[9]aneN₃)]²⁺, and [Pd(Me₃[9]aneN₃)(NCMe)₂]²⁺

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