Issue 1, 1993

Preparation of β-bromodifluoromethyl-functionalized esters, nitrile and ketones via addition of dibromodifluoromethane to electron-deficient alkenes initiated by a CrCl3/Fe bimetal redox system

Abstract

The addition of dibromodifluoromethane to electron-deficient alkenes proceeds smoothly in the presence of a CrCl3/Fe bimetal redox system, giving various β-bromodifluoromethyl-functionalized esters, nitriles and ketones in good yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1993, 72-73

Preparation of β-bromodifluoromethyl-functionalized esters, nitrile and ketones via addition of dibromodifluoromethane to electron-deficient alkenes initiated by a CrCl3/Fe bimetal redox system

C. Hu and J. Chen, J. Chem. Soc., Chem. Commun., 1993, 72 DOI: 10.1039/C39930000072

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